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A Calculated Bang

Explosive Predictions and the Ideal Gas Law

By Melissa R. Eslinger, Carl E. Lundell, Ryan E. Rodriguez

A Calculated Bang


 

Abstract

This directed case study provides an opportunity to apply stoichiometry to combustion reactions of commonly used explosive materials. Initially, students apply modified Kistiakowsky-Wilson (K-W) rules, developed during World War II, to predict the reaction products from a given starting material. From the derived balanced equation, stoichiometric equivalents of products can be used to apply the ideal gas law (IGL) to predict measures of pressure, volume, and temperature. The IGL is a great exercise in stoichiometry and requires conversion of units in similar terms, common to the ideal gas constant. Although the case was written for the introductory chemistry classroom, it would be suitable for students in analytical chemistry courses who need additional practice in stoichiometry.

   

Date Posted

06/01/2020

Overview

Objectives

  • Predict the products and balance the reaction for the combustion of an explosive material.
  • Apply the ideal gas law and stoichiometry to calculate amounts of reactants and products in a chemical reaction.

Keywords

Combustion reaction; stoichiometry; ideal gas law; chemical reactions; reaction products; analytical chemistry; explosives; Kistiakowsky-Wilson; K-W rules; PETN; dimensional analysis

  

Subject Headings

Analytical Chemistry
Chemistry (General)

EDUCATIONAL LEVEL

High school, Undergraduate lower division

  

FORMAT

PDF, PowerPoint

   

TOPICAL AREAS

History of science

   

LANGUAGE

English

   

TYPE/METHODS

Directed

 

 

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