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Fuel from Water and the Sun

An Application of Electrochemistry and Thermodynamics

By Joshua D. Hartman, Jack F. Eichler

Fuel from Water and the Sun


 

Abstract

This problem-based case study presents recent advancements in the development and application of technologies geared towards harnessing sunlight for the production of hydrogen from water. A PowerPoint presentation introduces the topic with a New York Times excerpt about a growing market of fuel cell-powered toys. Might similar technologies also address our transportation needs? Students next read a general overview from Chemical & Engineering News about the challenges associated with developing robust and economically feasible water-splitting catalysts and the recent development of a low-cost heterogeneous cobalt phosphate catalyst. Students also read a primary literature article from Science on the cobalt phosphate catalyst and then complete a three-page worksheet (included in the teaching notes) as a collaborative learning activity designed to increase understanding of the basic electrochemical principles underlying hydrogen production. This case study was originally written for a second semester/third quarter general chemistry course and presented after the units on thermodynamics and electrochemistry have been covered.

   

Date Posted

09/10/2015

Overview

Objectives

  • Highlight the relevance of chemistry to current world issues.
  • Apply basic chemical knowledge to complex, multi-faceted problems.
  • Develop the ability to critically analyze primary literature and draw conclusions based on the data and evidence contained therein.
  • Develop the ability to communicate scientific and technical concepts in both written and verbal form.
  • Improve the development of fundamental chemistry skills such as identifying half-reactions, calculating cell potentials, using tables of standard reduction potentials as well as the relation of free energy and cell potential.

Keywords

Electrochemistry; electrolysis; hydrogen fuel; alternative fuels; PEC; photoelectrochemical cells; thermodynamics; renewable fuels; half-reactions; cell potentials; standard reduction potentials; free energy

  

Subject Headings

Chemical Engineering
Chemistry (General)
Environmental Science

EDUCATIONAL LEVEL

Undergraduate lower division

  

FORMAT

PDF, PowerPoint

   

TOPICAL AREAS

Policy issues

   

LANGUAGE

English

   

TYPE/METHODS

Analysis (Issues), Journal Article, Problem-Based Learning

 

 

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